Search results for "Semi open"
showing 1 items of 1 documents
A facile semi-open method for synthesis of non-centrosymmetric superconducting Li2(Pd,Pt)3B bulks and thin films
2010
Abstract Non-centrosymmetric superconductor Li 2 (Pd 1− x Pt x ) 3 B, x = 0–1 was synthesized from mixtures of the elements. A simple semi-open method is proposed using endings-pressed stainless steel tubes placed in a high-vacuum furnace. Heating regime employed a short-time overheating at 900 °C and a slow cooling step between T s and 550 °C within 3 h. To adequately compensate Li-losses and attain maximum critical temperature, the optimum T s and starting Li-content were found to change from 720 to 740 °C and from Li 2.4 to Li 2.6 , respectively, when x was changing from 0 to 1. It was shown that placing Li separately in the tube also produces superconducting samples, Li being supplied …